dangerous of radioactive

Radioactive waste is a waste product containing radioactive material. It is usually the product of a nuclear process such as nuclear fission. However, industries not directly connected to the nuclear industry may produce quantities of radioactive waste. The majority of radioactive waste is "low-level waste", meaning it contains low levels of radioactivity per mass or volume. This type of waste often consists of used protective clothing, which is only lightly contaminated but still dangerous in case of radioactive contamination of a human body through ingestion, inhalation, absorption, or injection.
The issue of disposal methods for nuclear waste was one of the most pressing current problems the international nuclear industry faced when trying to establish a long term energy production plan, yet there was hope it could be safely solved. A report giving the Nuclear Industry's perspective on this problem is presented in a document from the IAEA (The International Atomic Energy Agency) published in October 2007. It summarizes the current state of scientific knowledge on whether waste could find its way from a deep burial facility back to soil and drinking water and threaten the health of human beings and other forms of life. In the United States, DOE acknowledges progress in addressing the waste problems of the industry, and successful remediation of some contaminated sites, yet some uncertainty and complications in handling the issue properly, cost effectively, and in the projected time frame.[1] In other countries with lower ability or will to maintain environmental integrity the issue would be even more problematic.
In the United States alone, the Department of Energy states there are "millions of gallons of radioactive waste" as well as "thousands of tons of spent nuclear fuel and material" and also "huge quantities of contaminated soil and water."[1] Despite copious quantities of waste, the DOE has stated a goal of cleaning all presently contaminated sites successfully by 2025.[1] The Fernald, Ohio site for example had "31 million pounds of uranium product", "2.5 billion pounds of waste", "2.75 million cubic yards of contaminated soil and debris", and a "223 acre portion of the underlying Great Miami Aquifer had uranium levels above drinking standards."[1] The United States has at least 108 sites designated as areas that are contaminated and unusable, sometimes many thousands of acres.[1][2] DOE wishes to clean or mitigate many or all by 2025, however the task can be difficult and it acknowledges that some may never be completely remediated. In just one of these 108 larger designations, Oak Ridge National Laboratory, there were for example at least "167 known contaminant release sites" in one of the three subdivisions of the 37,000-acre (150 km2) site.[1] Some of the U.S. sites were smaller in nature, however, cleanup issues were simpler to address, and DOE has successfully completed cleanup, or at least closure, of several sites.[1]
Claims exist that the problems of nuclear waste do not come anywhere close to approaching the problems of fossil fuel waste.[3][4] A 2004 article from the BBC states: "The World Health Organization (WHO) says 3 million people are killed worldwide by outdoor air pollution annually from vehicles and industrial emissions, and 1.6 million indoors through using solid fuel."[5] In the U.S. alone, fossil fuel waste has been linked to the death of 20,000 people each year.[6] A coal power plant releases 100 times as much radiation as a nuclear power plant of the same wattage.[7] It is estimated that during 1982, US coal burning released 155 times as much radioactivity into the atmosphere as the Three Mile Island accident.[8]
The World Nuclear Association provides a comparison of deaths due to accidents among different forms of energy production. In their comparison, deaths per TW-yr of electricity produced from 1970 to 1992 are quoted as 885 for hydropower, 342 for coal, 85 for natural gas, and 8 for nuclear.[9]

The nature and significance of radioactive waste
Radioactive waste typically comprises a number of radioisotopes: unstable configurations of elements that decay, emitting ionizing radiation which can be harmful to human health and to the environment. Those isotopes emit different types and levels of radiation, which last for different periods of time..
[Physics
Medium-lived
fission products

Prop:
Unit: t½
a
Yield
% Q *
KeV
βγ
*
155Eu
4.76 .0803 252 βγ
85Kr
10.76 .2180 687 βγ
113mCd
14.1 .0008 316 β
90Sr
28.9 4.505 2826 β
137Cs
30.23 6.337 1176 βγ
121mSn
43.9 .00005 390 βγ
151Sm
90 .5314 77 β
Long-lived
fission products

Prop:
Unit: t½
Ma
Yield
% Q *
KeV
βγ
*
99Tc
0.211 6.1385 294 β
126Sn
0.230 0.1084 4050 βγ
79Se
0.295 0.0447 151 β
93Zr
1.53 5.4575 91 βγ
135Cs
2.3 6.9110 269 β
107Pd
6.5 1.2499 33 β
129I
15.7 0.8410 194 βγ
The radioactivity of all nuclear waste diminishes with time. All radioisotopes contained in the waste have a half-life - the time it takes for any radionuclide to lose half of its radioactivity and eventually all radioactive waste decays into non-radioactive elements. Certain radioactive elements (such as plutonium-239) in “spent” fuel will remain hazardous to humans and other living beings for hundreds of thousands of years. Other radioisotopes remain hazardous for millions of years. Thus, these wastes must be shielded for centuries and isolated from the living environment for millennia.[10] Some elements, such as Iodine-131, have a short half-life (around 8 days in this case) and thus they will cease to be a problem much more quickly than other, longer-lived, decay products but their activity is much greater initially. The two tables show some of the major radioisotopes, their half-lives, and their radiation yield as a proportion of the yield of fission of Uranium-235.
The faster a radioisotope decays, the more radioactive it will be. The energy and the type of the ionizing radiation emitted by a pure radioactive substance are important factors in deciding how dangerous it will be. The chemical properties of the radioactive element will determine how mobile the substance is and how likely it is to spread into the environment and contaminate human bodies. This is further complicated by the fact that many radioisotopes do not decay immediately to a stable state but rather to a radioactive decay product leading to decay chains.
Pharmacokinetics
Actinides
Halflife
Fission products

244Cm
241Pu f
250Cf
243Cmf
10–30 y 137Cs
90Sr
85Kr

232U f
238Pu
f is for
fissile
69–90 y 151Sm nc➔

4n
249Cf f
242Amf
141–351 No fission product
has halflife 102
to 2×105 years
241Am
251Cf f
431–898
240Pu
229Th
246Cm
243Am
5–7 ky
4n
245Cmf
250Cm
239Pu f
8–24 ky
233U f
230Th
231Pa
32–160
4n+1
234U
4n+3
211–290 99Tc
126Sn
79Se

248Cm
242Pu
340–373 Long-lived fission products

237Np
4n+2
1–2 my 93Zr
135Cs nc➔

236U
4n+1
247Cmf
6–23 107Pd
129I

244Pu
80 my >7% >5% >1% >.1%
232Th
238U
235U f
0.7–12by fission product yield

Exposure to high levels of radioactive waste may cause serious harm or death. Treatment of an adult animal with radiation or some other mutation-causing effect, such as a cytotoxic anti-cancer drug, may cause cancer in the animal. In humans it has been calculated that a 5 sievert dose is usually fatal, and the lifetime risk of dying from radiation induced cancer from a single dose of 0.1 sieverts is 0.8%, increasing by the same amount for each additional 0.1 sievert increment of dosage.[11] Ionizing radiation causes deletions in chromosomes.[12] If a developing organism such as an unborn child is irradiated, it is possible a birth defect may be induced, but it is unlikely this defect will be in a gamete or a gamete forming cell. The incidence of radiation-induced mutations in humans is undetermined, due to flaws in studies done to date.
Depending on the decay mode and the pharmacokinetics of an element (how the body processes it and how quickly), the threat due to exposure to a given activity of a radioisotope will differ. For instance iodine-131 is a short-lived beta and gamma emitter but because it concentrates in the thyroid gland, it is more able to cause injury than caesium-137 which, being water soluble, is rapidly excreted in urine. In a similar way, the alpha emitting actinides and radium are considered very harmful as they tend to have long biological half-lives and their radiation has a high linear energy transfer value. Because of such differences, the rules determining biological injury differ widely according to the radioisotope, and sometimes also the nature of the chemical compound which contains the radioisotope.
Goals of waste management
The main objective in managing and disposing or destruction of radioactive (or other) waste is to protect people and the environment. This means isolating, diluting, or destroying (transmutating) the waste so that the rate or concentration of any radionuclide returned to the biosphere is harmless. To achieve this the preferred technology to date has been deep and secure burial for the more dangerous wastes; transmutation, long-term retrievable storage, and removal to space have also been suggested. Management options for waste are discussed below.
Radioactivity by definition reduces over time, so in principle the waste needs to be isolated for a particular period of time until its components have decayed such that it no longer poses a threat. In practice this can mean periods of hundreds of thousands of years, depending on the nature of the waste involved.
Though an affirmative answer is often taken for granted, the question as to whether or not we should endeavor to avoid causing harm to remote future generations, perhaps thousands upon thousands of years hence, is essentially one which must be dealt with by philosophy.
Sources of waste
Radioactive waste comes from a number of sources. The majority of waste originates from the nuclear fuel cycle and nuclear weapons reprocessing. However, other sources include medical and industrial wastes, as well as naturally occurring radioactive materials (NORM) that can be concentrated as a result of the processing or consumption of coal, oil and gas, and some minerals, as discussed below.
Nuclear fuel cycle
] Front end
Waste from the front end of the nuclear fuel cycle is usually alpha emitting waste from the extraction of uranium. It often contains radium and its decay products.
Uranium dioxide (UO2) concentrate from mining is not very radioactive - only a thousand or so times as radioactive as the granite used in buildings. It is refined from yellowcake (U3O8), then converted to uranium hexafluoride gas (UF6). As a gas, it undergoes enrichment to increase the U-235 content from 0.7% to about 4.4% (LEU). It is then turned into a hard ceramic oxide (UO2) for assembly as reactor fuel elements.
The main by-product of enrichment is depleted uranium (DU), principally the U-238 isotope, with a U-235 content of ~0.3%. It is stored, either as UF6 or as U3O8. Some is used in applications where its extremely high density makes it valuable, such as the keels of yachts, and anti-tank shells. It is also used (with recycled plutonium) for making mixed oxide fuel (MOX) and to dilute highly enriched uranium from weapons stockpiles which is now being redirected to become reactor fuel. This dilution, also called downblending, means that any nation or group that acquired the finished fuel would have to repeat the (very expensive and complex) enrichment process before assembling a weapon.
Back end
The back end of the nuclear fuel cycle, mostly spent fuel rods, contains fission products that emit beta and gamma radiation, and actinides that emit alpha particles, such as uranium-234, neptunium-237, plutonium-238 and americium-241, and even sometimes some neutron emitters such as californium (Cf). These isotopes are formed in nuclear reactors.
It is important to distinguish the processing of uranium to make fuel from the reprocessing of used fuel. Used fuel contains the highly radioactive products of fission (see high level waste below). Many of these are neutron absorbers, called neutron poisons in this context. These eventually build up to a level where they absorb so many neutrons that the chain reaction stops, even with the control rods completely removed. At that point the fuel has to be replaced in the reactor with fresh fuel, even though there is still a substantial quantity of uranium-235 and plutonium present. In the United States, this used fuel is stored, while in countries such as the Russia,United Kingdom, France, Japan and India the fuel is reprocessed to remove the fission products, and the fuel can then be re-used. This reprocessing involves handling highly radioactive materials, and the fission products removed from the fuel are a concentrated form of high-level waste as are the chemicals used in the process. While these countries reprocess the fuel carrying out single plutonium cycles, India is known to be the only country in the world planning multiple plutonium recycling schemes.. This has two distinct advantages, the reprocessed fuel is rendered unusable for weapons development, and high fuel efficiency can be achieved. For their plutonium generating reactors, India has realized a burn-up almost 4 times as high as the typical fuel efficiency of normal commercial nuclear reactors.[
Fuel composition and long term radioactivity


Activity of U-233 for three fuel types


Total activity for three fuel types
Long-lived radioactive waste form the back end of the fuel cycle is especially relevant when designing a complete waste management plan for spent nuclear fuel (SNF). When looking at long term radioactive decay, the actinides in the SNF have a significant influence due to their characteristically long half-lives. Depending on what a nuclear reactor is fueled with, the actinide composition in the SNF will be different.
An example of this effect is the use of nuclear fuels with thorium. Th-232 is a fertile material that can undergo a neutron capture reaction and two beta minus decays, resulting in the production of fissile U-233. The SNF of a cycle with thorium will contain U-233, an isotope with a half-life of 1.59E5 years. Its radioactive decay will strongly influence the long-term activity curve of the SNF around 10E5 years. A comparison of the activity associated to U-233 for three different SNF types can be seen in the figure on the top right.
The burnt fuels are thorium with reactor-grade plutonium (RGPu), thorium with weapons-grade plutonium (WGPu) and Mixed Oxide fuel (MOX). For RGPu and WGPu, the initial amount of U-233 and its decay around 10E5 years can be seen. This has an effect in the total activity curve of the three fuel types. The absence of U-233 and its daughter products in the MOX fuel results in a lower activity in region 3 of the figure on the bottom right, whereas for RGPu and WGPu the curve is maintained higher due to the presence of U-233 that has not fully decayed.
The use of different fuels in nuclear reactors results in different SNF composition, with varying activity curves.
[edit] Proliferation concerns
Main article: Nuclear proliferation
When dealing with uranium and plutonium, the possibility that they may be used to build nuclear weapons is often a concern. Active nuclear reactors and nuclear weapons stockpiles are very carefully safeguarded and controlled. However, high-level waste from nuclear reactors may contain plutonium. Ordinarily, this plutonium is reactor-grade plutonium, containing a mixture of plutonium-239 (highly suitable for building nuclear weapons), plutonium-240 (an undesirable contaminant and highly radioactive), plutonium-241, and plutonium-238; these isotopes are difficult to separate. Moreover, high-level waste is full of highly radioactive fission products. However, most fission products are relatively short-lived. This is a concern since if the waste is stored, perhaps in deep geological storage, over many years the fission products decay, decreasing the radioactivity of the waste and making the plutonium easier to access. Moreover, the undesirable contaminant Pu-240 decays faster than the Pu-239, and thus the quality of the bomb material increases with time (although its quantity decreases during that time as well). Thus, some have argued, as time passes, these deep storage areas have the potential to become "plutonium mines", from which material for nuclear weapons can be acquired with relatively little difficulty. Critics of the latter idea point out that the half-life of Pu-240 is 6,560 years and Pu-239 is 24,110 years, and thus the relative enrichment of one isotope to the other with time occurs with a half-life of 9,000 years (that is, it takes 9000 years for the fraction of Pu-240 in a sample of mixed plutonium isotopes, to spontaneously decrease by half—a typical enrichment needed to turn reactor-grade into weapons-grade Pu). Thus "weapons grade plutonium mines" would be a problem for the very far future (>9,000 years from now), so that there remains a great deal of time for technology to advance to solve this problem, before it becomes acute.
Pu-239 decays to U-235 which is suitable for weapons and which has a very long half life (roughly 109 years). Thus plutonium may decay and leave uranium-235. However, modern reactors are only moderately enriched with U-235 relative to U-238, so the U-238 continues to serve as denaturation agent for any U-235 produced by plutonium decay.
One solution to this problem is to recycle the plutonium and use it as a fuel e.g. in fast reactors. But in the minds of some, the very existence of the nuclear fuel reprocessing plant needed to separate the plutonium from the other elements represents a proliferation concern. In pyrometallurgical fast reactors, the waste generated is an actinide compound that cannot be used for nuclear weapons.
[edit] Nuclear weapons reprocessing
Waste from nuclear weapons reprocessing (as opposed to production, which requires primary processing from reactor fuel) is unlikely to contain much beta or gamma activity other than tritium and americium. It is more likely to contain alpha emitting actinides such as Pu-239 which is a fissile material used in bombs, plus some material with much higher specific activities, such as Pu-238 or Po.
In the past the neutron trigger for a bomb tended to be beryllium and a high activity alpha emitter such as polonium; an alternative to polonium is Pu-238. For reasons of national security, details of the design of modern bombs are normally not released to the open literature. It is likely however that a D-T fusion reaction in either an electrically driven device or a D-T fusion reaction driven by the chemical explosives would be used to start up a modern device.
Some designs might well contain a radioisotope thermoelectric generator using Pu-238 to provide a longlasting source of electrical power for the electronics in the device.
It is likely that the fissile material of an old bomb which is due for refitting will contain decay products of the plutonium isotopes used in it, these are likely to include U-236 from Pu-240 impurities, plus some U-235 from decay of the Pu-239; however, due to the relatively long half-life of these Pu isotopes, these wastes from radioactive decay of bomb core material would be very small, and in any case, far less dangerous (even in terms of simple radioactivity) than the Pu-239 itself.
The beta decay of Pu-241 forms Am-241; the in-growth of americium is likely to be a greater problem than the decay of Pu-239 and Pu-240 as the americium is a gamma emitter (increasing external-exposure to workers) and is an alpha emitter which can cause the generation of heat. The plutonium could be separated from the americium by several different processes; these would include pyrochemical processes and aqueous/organic solvent extraction. A truncated PUREX type extraction process would be one possible method of making the separation.
Medical
Radioactive medical waste tends to contain beta particle and gamma ray emitters. It can be divided into two main classes. In diagnostic nuclear medicine a number of short-lived gamma emitters such as technetium-99m are used. Many of these can be disposed of by leaving it to decay for a short time before disposal as normal waste. Other isotopes used in medicine, with half-lives in parentheses:
• Y-90, used for treating lymphoma (2.7 days)
• I-131, used for thyroid function tests and for treating thyroid cancer (8.0 days)
• Sr-89, used for treating bone cancer, intravenous injection (52 days)
• Ir-192, used for brachytherapy (74 days)
• Co-60, used for brachytherapy and external radiotherapy (5.3 years)
• Cs-137, used for brachytherapy, external radiotherapy (30 years)
Industrial
Industrial source waste can contain alpha, beta, neutron or gamma emitters. Gamma emitters are used in radiography while neutron emitting sources are used in a range of applications, such as oil well logging.[16]
Naturally occurring radioactive material (NORM)
Processing of substances containing natural radioactivity; this is often known as NORM. A lot of this waste is alpha particle-emitting matter from the decay chains of uranium and thorium. The main source of radiation in the human body is potassium-40 (40K). There is a natural background radioactivity that life systems are built to resist. Most rocks, due to their components, have a certain, but low level, of radioactivity.
Coal
Coal contains a small amount of radioactive uranium, barium, thorium and potassium, but, in the case of pure coal, this is significantly less than the average concentration of those elements in the Earth's crust. However, the surrounding strata, if shale or mudstone, often contains slightly more than average and this may also be reflected in the ash content of 'dirty' coals[17].[18] The more active ash minerals become concentrated in the fly ash precisely because they do not burn well.[18] However, the radioactivity of fly ash is still very low. It is about the same as black shale and is less than phosphate rocks, but is more of a concern because a small amount of the fly ash ends up in the atmosphere where it can be inhaled.[19]
Oil and gas
Residues from the oil and gas industry often contain radium and its daughters. The sulphate scale from an oil well can be very radium rich, while the water, oil and gas from a well often contains radon. The radon decays to form solid radioisotopes which form coatings on the inside of pipework. In an oil processing plant the area of the plant where propane is processed is often one of the more contaminated areas of the plant as radon has a similar boiling point as propane.[20]
Types of radioactive waste


Removal of very low-level waste
Although not significantly radioactive, uranium mill tailings are waste. They are byproduct material from the rough processing of uranium-bearing ore. They are sometimes referred to as 11(e)2 wastes, from the section of the U.S. Atomic Energy Act that defines them. Uranium mill tailings typically also contain chemically-hazardous heavy metals such as lead and arsenic. Vast mounds of uranium mill tailings are left at many old mining sites, especially in Colorado, New Mexico, and Utah.
Low level waste (LLW) is generated from hospitals and industry, as well as the nuclear fuel cycle. It comprises paper, rags, tools, clothing, filters, etc., which contain small amounts of mostly short-lived radioactivity. Commonly, LLW is designated as such as a precautionary measure if it originated from any region of an 'Active Area', which frequently includes offices with only a remote possibility of being contaminated with radioactive materials. Such LLW typically exhibits no higher radioactivity than one would expect from the same material disposed of in a non-active area, such as a normal office block. Some high activity LLW requires shielding during handling and transport but most LLW is suitable for shallow land burial. To reduce its volume, it is often compacted or incinerated before disposal. Low level waste is divided into four classes, class A, B, C and GTCC, which means "Greater Than Class C".
Intermediate level waste (ILW) contains higher amounts of radioactivity and in some cases requires shielding. ILW includes resins, chemical sludge and metal reactor fuel cladding, as well as contaminated materials from reactor decommissioning. It may be solidified in concrete or bitumen for disposal. As a general rule, short-lived waste (mainly non-fuel materials from reactors) is buried in shallow repositories, while long-lived waste (from fuel and fuel-reprocessing) is deposited in deep underground facilities. U.S. regulations do not define this category of waste; the term is used in Europe and elsewhere.


High Level Waste flasks are transported by train in the United Kingdom. Each flask is constructed of 14 in (360 mm) thick solid steel and weighs in excess of 50 tons
High level waste (HLW) is produced by nuclear reactors. It contains fission products and transuranic elements generated in the reactor core. It is highly radioactive and often thermally hot. HLW accounts for over 95% of the total radioactivity produced in the process of nuclear electricity generation. The amount of HLW worldwide is currently increasing by about 12,000 metric tons every year, which is the equivalent to about 100 double-decker busses or a two-story structure with a footprint the size of a basketball court.[21]
Transuranic waste (TRUW) as defined by U.S. regulations is, without regard to form or origin, waste that is contaminated with alpha-emitting transuranic radionuclides with half-lives greater than 20 years, and concentrations greater than 100 nCi/g (3.7 MBq/kg), excluding High Level Waste. Elements that have an atomic number greater than uranium are called transuranic ("beyond uranium"). Because of their long half-lives, TRUW is disposed more cautiously than either low level or intermediate level waste. In the U.S. it arises mainly from weapons production, and consists of clothing, tools, rags, residues, debris and other items contaminated with small amounts of radioactive elements (mainly plutonium).
Under U.S. law, Transuranic waste is further categorized into "contact-handled" (CH) and "remote-handled" (RH) on the basis of radiation dose measured at the surface of the waste container. CH TRUW has a surface dose rate not greater than 200 mrem per hour (2 mSv/h), whereas RH TRUW has a surface dose rate of 200 mrem per hour (2 mSv/h) or greater. CH TRUW does not have the very high radioactivity of high level waste, nor its high heat generation, but RH TRUW can be highly radioactive, with surface dose rates up to 1000000 mrem per hour (10000 mSv/h). The United States currently permanently disposes of TRUW generated from nuclear power plants and military facilities at the Waste Isolation Pilot Plant.[22]
Management of waste
See also: High-level radioactive waste management
Of particular concern in nuclear waste management are two long-lived fission products, Tc-99 (half-life 220,000 years) and I-129 (half-life 17 million years), which dominate spent fuel radioactivity after a few thousand years. The most troublesome transuranic elements in spent fuel are Np-237 (half-life two million years) and Pu-239 (half life 24,000 years Nuclear waste requires sophisticated treatment and management in order to successfully isolate it from interacting with the biosphere. This usually necessitates treatment, followed by a long-term management strategy involving storage, disposal or transformation of the waste into a non-toxic form Governments around the world are considering a range of waste management and disposal options, though there has been limited progress toward long-term waste management solutions.
Initial treatment of waste
Vitrification


A vitrification experiment for the study of nuclear waste disposal
Long-term storage of radioactive waste requires the stabilization of the waste into a form which will not react, nor degrade, for extended periods of time. One way to do this is through vitrification Currently at Sellafield the high-level waste (PUREX first cycle raffinate) is mixed with sugar and then calcined. Calcination involves passing the waste through a heated, rotating tube. The purposes of calcination are to evaporate the water from the waste, and de-nitrate the fission products to assist the stability of the glass produce
The 'calcine' generated is fed continuously into an induction heated furnace with fragmented glass. The resulting glass is a new substance in which the waste products are bonded into the glass matrix when it solidifies. This product, as a molten fluid, is poured into stainless steel cylindrical containers ("cylinders") in a batch process. When cooled, the fluid solidifies ("vitrifies") into the glass. Such glass, after being formed, is very highly resistant to water.
After filling a cylinder, a seal is welded onto the cylinder. The cylinder is then washed. After being inspected for external contamination, the steel cylinder is stored, usually in an underground repository. In this form, the waste products are expected to be immobilized for a very long period of time (many thousands of years
The glass inside a cylinder is usually a black glossy substance. All this work (in the United Kingdom) is done using hot cell systems. The sugar is added to control the ruthenium chemistry and to stop the formation of the volatile RuO4 containing radio ruthenium. In the west, the glass is normally a borosilicate glass (similar to Pyrex), while in the former Soviet bloc it is normal to use a phosphate glass. The amount of fission products in the glass must be limited because some (palladium, the other Pt group metals, and tellurium) tend to form metallic phases which separate from the glass. Bulk vitrification uses electrodes to melt soil and wastes, which are then buried underground.[ In Germany a vitrification plant is in use; this is treating the waste from a small demonstration reprocessing plant which has since been closed down.[27][32]
[edit] Ion exchange
It is common for medium active wastes in the nuclear industry to be treated with ion exchange or other means to concentrate the radioactivity into a small volume. The much less radioactive bulk (after treatment) is often then discharged. For instance, it is possible to use a ferric hydroxide floc to remove radioactive metals from aqueous mixtures [1]. After the radioisotopes are absorbed onto the ferric hydroxide, the resulting sludge can be placed in a metal drum before being mixed with cement to form a solid waste form.[33] In order to get better long-term performance (mechanical stability) from such forms, they may be made from a mixture of fly ash, or blast furnace slag, and portland cement, instead of normal concrete (made with portland cement, gravel and sand).
Synroc
The Australian Synroc (synthetic rock) is a more sophisticated way to immobilize such waste, and this process may eventually come into commercial use for civil wastes (it is currently being developed for U.S. military wastes). Synroc was invented by the late Prof Ted Ringwood (a geochemist) at the Australian National University.[34] The Synroc contains pyrochlore and cryptomelane type minerals. The original form of Synroc (Synroc C) was designed for the liquid high level waste (PUREX raffinate) from a light water reactor. The main minerals in this Synroc are hollandite (BaAl2Ti6O16), zirconolite (CaZrTi2O7) and perovskite (CaTiO3). The zirconolite and perovskite are hosts for the actinides. The strontium and barium will be fixed in the perovskite. The caesium will be fixed in the hollandite.
Long term management of waste
See also: Economics of new nuclear power plants#Waste disposal
The timeframe in question when dealing with radioactive waste ranges from 10,000 to 1,000,000 years, according to studies based on the effect of estimated radiation doses. Researchers suggest that forecasts of health detriment for such periods should be examined critically. Practical studies only consider up to 100 years as far as effective planning and cost evaluations are concerned. Long term behavior of radioactive wastes remains a subject for ongoing research projects.
Geologic disposal
The process of selecting appropriate deep final repositories for high level waste and spent fuel is now under way in several countries (Schacht Asse II and the waste Isolation Pilot Plant) with the first expected to be commissioned some time after 2010. The basic concept is to locate a large, stable geologic formation and use mining technology to excavate a tunnel, or large-bore tunnel boring machines (similar to those used to drill the Chunnel from England to France) to drill a shaft 500–1,000 meters below the surface where rooms or vaults can be excavated for disposal of high-level radioactive waste. The goal is to permanently isolate nuclear waste from the human environment. However, many people remain uncomfortable with the immediate stewardship cessation of this disposal system, suggesting perpetual management and monitoring would be more prudent.
Because some radioactive species have half-lives longer than one million years, even very low container leakage and radionuclide migration rates must be taken into account. Moreover, it may require more than one half-life until some nuclear materials lose enough radioactivity to no longer be lethal to living things. A 1983 review of the Swedish radioactive waste disposal program by the National Academy of Sciences found that country’s estimate of several hundred thousand years—perhaps up to one million years—being necessary for waste isolation “fully justified.” Storing high level nuclear waste above ground for a century or so is considered appropriate by many scientists. This allows the material to be more easily observed and any problems detected and managed, while decay of radionuclides over this time period significantly reduces the level of radioactivity and associated harmful effects to the container material. It is also considered likely that over the next century newer materials will be developed which will not break down as quickly when exposed to a high neutron flux, thus increasing the longevity of the container once it is permanently buried.
Sea-based options for disposal of radioactive waste include burial beneath a stable abyssal plain, burial in a subduction zone that would slowly carry the waste downward into the Earth's mantle, and burial beneath a remote natural or human-made island. While these approaches all have merit and would facilitate an international solution to the vexing problem of disposal of radioactive waste, they are currently not being seriously considered because of the legal barrier of the Law of the Sea and because in North America and Europe sea-based burial has become taboo from fear that such a repository could leak and cause widespread damage. Dumping of radioactive waste from ships has reinforced this concern, as has contamination of islands in the Pacific Ocean. However, sea-based approaches might come under consideration in the future by individual countries or groups of countries that cannot find other acceptable solutions.
Article 1 (Definitions), 7., of the 1996 Protocol to the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter, (the London Dumping Convention) states:
“Sea” means all marine waters other than the internal waters of States, as well as the seabed and the subsoil thereof; it does not include sub-seabed repositories accessed only from land.”
The proposed land-based subductive waste disposal method disposes of nuclear waste in a subduction zone accessed from land,] and therefore is not prohibited by international agreement. This method has been described as the most viable means of disposing of radioactive waste, and as the state-of-the-art in nuclear waste disposal technology. Another approach termed Remix & Return[ would blend high-level waste with uranium mine and mill tailings down to the level of the original radioactivity of the uranium ore, then replace it in inactive uranium mines. This approach has the merits of providing jobs for miners who would double as disposal staff, and of facilitating a cradle-to-grave cycle for radioactive materials. However, this approach would be inappropriate for spent reactor fuel in the absence of reprocessing, due to the presence in it of highly toxic radioactive elements such as plutonium.
[edit] Transmutation
Main article: Nuclear transmutation
There have been proposals for reactors that consume nuclear waste and transmute it to other, less-harmful nuclear waste. In particular, the Integral Fast Reactor was a proposed nuclear reactor with a nuclear fuel cycle that produced no transuranic waste and in fact, could consume transuranic waste. It proceeded as far as large-scale tests but was then canceled by the U.S. Government. Another approach, considered safer but requiring more development, is to dedicate subcritical reactors to the transmutation of the left-over transuranic elements.
An isotope that is found in nuclear waste and that represents a concern in terms of proliferation is Pu-239. The estimated world total of plutonium in the year 2000 was of 1,645 MT, of which 210 MT had been separated by reprocessing. The large stock of plutonium is a result of its production inside uranium-fueled reactors and of the reprocessing of weapons-grade plutonium during the weapons program. An option for getting rid of this plutonium is to use it as a fuel in a traditional Light Water Reactor (LWR). Several fuel types with differing plutonium destruction efficiencies are under study. See Nuclear transmutation.
Transmutation was banned in the United States on April 1977 by President Carter due to the danger of plutonium proliferation, but President Reagan rescinded the ban in 1981. Due to the economic losses and risks, construction of reprocessing plants during this time did not resume. Due to high energy demand, work on the method has continued in the EU. This has resulted in a practical nuclear research reactor called Myrrha in which transmutation is possible. Additionally, a new research program called ACTINET has been started in the EU to make transmutation possible on a large, industrial scale. According to President Bush's Global Nuclear Energy Partnership (GNEP) of 2007, the United States is now actively promoting research on transmutation technologies needed to markedly reduce the problem of nuclear waste treatment.
There have also been theoretical studies involving the use of fusion reactors as so called "actinide burners" where a fusion reactor plasma such as in a tokamak, could be "doped" with a small amount of the "minor" transuranic atoms which would be transmuted (meaning fissioned in the actinide case) to lighter elements upon their successive bombardment by the very high energy neutrons produced by the fusion of deuterium and tritium in the reactor. It was recently found by a study done at MIT, that only 2 or 3 fusion reactors with parameters similar to that of the International Thermonuclear Experimental Reactor (ITER) could transmute the entire annual minor actinide production from all of the light water reactors presently operating in the United States fleet while simultaneously generating approximately 1 gigawatt of power from each reactor[2].
[edit] Re-use of waste
Another option is to find applications of the isotopes in nuclear waste so as to re-use them.[51] Already, caesium-137, strontium-90 and a few other isotopes are extracted for certain industrial applications such as food irradiation and radioisotope thermoelectric generators. While re-use does not eliminate the need to manage radioisotopes, it may reduce the quantity of waste produced.
The Nuclear Assisted Hydrocarbon Production Method,[ Canadian patent application 2,659,302, is a method for the temporary or permanent storage of nuclear waste materials comprising the placing of waste materials into one or more repositories or boreholes constructed into an unconventional oil formation. The thermal flux of the waste materials fracture the formation, alters the chemical and/or physical properties of hydrocarbon material within the subterranean formation to allow removal of the altered material. A mixture of hydrocarbons, hydrogen, and/or other formation fluids are produced from the formation. The radioactivity of high-level radioactive waste affords proliferation resistance to plutonium placed in the periphery of the repository or the deepest portion of a borehole.
A 1990 proposed type of breeder reactor called a traveling wave reactor is claimed, if it were to be built, to be able to be fueled by depleted uranium, which is currently considered nuclear waste.
Space disposal
Space disposal is an attractive notion because it permanently removes nuclear waste from the environment. However, it has significant disadvantages, not least of which is the potential for catastrophic failure of a launch vehicle. Furthermore, the high number of launches that would be required — due to the fact that no individual rocket would be able to carry very much of the material relative to the material needed to be disposed of—makes the proposal impractical (for both economic and risk-based reasons). To further complicate matters, international agreements on the regulation of such a program would need to be established. [3] This method would also be energy intensive and thus is not necessarily economically feasible.
In the future, alternative, non-rocket spacelaunch technologies may provide a solution. It has been suggested that through the use of a stationary launch system many of the risks of catastrophic launch failure could be avoided. A promising concept is the use of high power lasers to launch "indestructible" containers from the ground into space. Such a system would require no rocket propellant, with the launch vehicle's payload making up a near entirety of the vehicle's mass. Without the use of rocket fuel on board there would be little chance of the vehicle exploding.
One possibility involves encasing the waste in glassified form inside a steel shell 9 inches (230 mm) thick, which in turn is tiled with shuttle tile to its exterior. If the launch vehicle fails just before reaching orbit, the waste ball will safely re-enter the Earth's atmosphere. The steel shell would deform on impact, but would not rupture due to the density of the shell. Also, this would potentially allow the waste to be shot into the Sun.[
] National management plans
See also: High-level radioactive waste management
Most countries are considerably ahead of the United States in developing plans for high-level radioactive waste disposal. Sweden and Finland are furthest along in committing to a particular disposal technology, while many others reprocess spent fuel or contract with France or Great Britain to do it, taking back the resulting plutonium and high-level waste. “An increasing backlog of plutonium from reprocessing is developing in many countries... It is doubtful that reprocessing makes economic sense in the present environment of cheap uranium.[
In many European countries (e.g., Britain, Finland, the Netherlands, Sweden and Switzerland) the risk or dose limit for a member of the public exposed to radiation from a future high-level nuclear waste facility is considerably more stringent than that suggested by the International Commission on Radiation Protection or proposed in the United States. European limits are often more stringent than the standard suggested in 1990 by the International Commission on Radiation Protection by a factor of 20, and more stringent by a factor of ten than the standard proposed by the U.S. Environmental Protection Agency (EPA) for Yucca Mountain nuclear waste repository for the first 10,000 years after closure. Moreover, the U.S. EPA’s proposed standard for greater than 10,000 years is 250 times more permissive than the European limit.[56]
Illegal dumping
Main article: Radioactive waste dumping by 'Ndrangheta
Authorities in Italy are investigating a 'Ndrangheta mafia clan accused of trafficking and illegally dumping nuclear waste. According to a turncoat, a manager of the Italy’s state energy research agency Enea paid the clan to get rid of 600 drums of toxic and radioactive waste from Italy, Switzerland, France, Germany, and the US, with Somalia as the destination, where the waste was buried after buying off local politicians. Former employees of Enea are suspected of paying the criminals to take waste off their hands in the 1980s and 1990s. Shipments to Somalia continued into the 1990s, while the 'Ndrangheta clan also blew up shiploads of waste, including radioactive hospital waste, and sending them to the sea bed off the Calabrian coast. According to the environmental group Legambiente, former members of the 'Ndrangheta have said that they were paid to sink ships with radioactive material for the last 20 years.
Accidents involving radioactive waste
Main article: Nuclear and radiation accidents
A number of incidents have occurred when radioactive material was disposed of improperly, shielding during transport was defective, or when it was simply abandoned or even stolen from a waste store. In the Soviet Union, waste stored in Lake Karachay was blown over the area during a dust storm after the lake had partly dried out. At Maxey Flat, a low-level radioactive waste facility located in Kentucky, containment trenches covered with dirt, instead of steel or cement, collapsed under heavy rainfall into the trenches and filled with water. The water that invaded the trenches became radioactive and had to be disposed of at the Maxey Flat facility itself. In other cases of radioactive waste accidents, lakes or ponds with radioactive waste accidentally overflowed into the rivers during exceptional storms.[citation needed] In Italy, several radioactive waste deposits let material flow into river water, thus contaminating water fit for domestic useIn France, in the summer of 2008 numerous incidents happened; in one, at the Areva plant in Tricastin, it was reported that during a draining operation liquid containing untreated uranium overflowed out of a faulty tank and about 75 kg of the radioactive material seeped into the ground and, from there, into two rivers nearby;; in another case, over 100 staff were contaminated with low doses of radiation. Scavenging of abandoned radioactive material has been the cause of several other cases of radiation exposure, mostly in developing nations, which may have less regulation of dangerous substances (and sometimes less general education about radioactivity and its hazards) and a market for scavenged goods and scrap metal. The scavengers and those who buy the material are almost always unaware that the material is radioactive and it is selected for its aesthetics or scrap value. Irresponsibility on the part of the radioactive material's owners, usually a hospital, university or military, and the absence of regulation concerning radioactive waste, or a lack of enforcement of such regulations, have been significant factors in radiation exposures. For an example of an accident involving radioactive scrap originating from a hospital see the Goiânia accident. Transportation accidents involving spent nuclear fuel from power plants are unlikely to have serious consequences due to the strength of the spent nuclear fuel shipping casks